Well I like CO2 being in the world. invisible sub
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Well I like CO2 being in the world.
invisible substance termed a "gas"
or "wild spirit" (spiritus sylvestris).[23]
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Other names
Carbonic acid gas
Carbonic anhydride
Carbonic oxide
Carbon oxide
Carbon(IV) oxide
Dry ice (solid phase)
In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products,[42] such as metal carbonates and bicarbonates.[citation needed] Some carboxylic acid derivatives such as sodium salicylate are prepared using CO
2 by the Kolbe-Schmitt reaction.[43]
In addition to conventional processes using CO
2 for chemical production, electrochemical methods are also being explored at a research level. In particular, the use of renewable energy for production of fuels from CO
2 (such as methanol) is attractive as this could result in fuels that could be easily transported and used within conventional combustion technologies but have no net CO
2 emissions.[44]
Foods
Carbon dioxide bubbles in a soft drink.
Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU[45] (listed as E number E290), US[46] and Australia and New Zealand[47] (listed by its INS number 290).
A candy called Pop Rocks is pressurized with carbon dioxide gas[48] at about 4 x 106 Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop.
Leavening agents cause dough to rise by producing carbon dioxide.[49] Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.
Beverages
Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.
Winemaking
Dry ice used to preserve grapes after harvest.
Carbon dioxide in the form of dry ice is often used during the cold soak phase in winemaking to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine.
Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.
Stunning animals
Carbon dioxide is often used to "stun" animals before slaughter.[50] "Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress.[51][52]
Inert gas
It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres.[citation needed] It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium.[citation needed] When used for MIG welding, CO
2 use is sometimes referred to as MAG welding, for Metal Active Gas, as CO
2 can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.
It is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi, 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of CO
2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines.[citation needed] High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy[53] and in the decaffeination of coffee beans.
Fire extinguisher
Use of a CO
2 fire extinguisher.
Carbon dioxide can be used to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances significantly and when the carbon dioxide disperses they are free to catch fire upon exposure to atmospheric oxygen. Their desirability in electrical fire stems from the fact that, unlike water or other chemical based methods, Carbon dioxide will not cause short circuits, leading to even more damage to equipment. Because it is a gas, it is also easy to dispense large amounts of the gas automatically in IT infrastructure rooms, where the fire itself might be hard to reach with more immediate methods because it is behind rack doors and inside of cases. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space.[54] International Maritime Organization standards also recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide based fire protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of CO
2 systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries.[55]
Supercritical CO2 as solvent
See also: Supercritical carbon dioxide
Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove caffeine from coffee.[15] Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides. It is also used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.
Agricultural and biological applications
Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional CO
2 to sustain and increase the rate of plant growth.[56][57] At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.[58]
It has been proposed that CO
2 from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel.[59]
Medical and pharmacological uses
In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O
2/CO
2 balance in blood.
Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses.
Oil recovery
Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by between 7% to 23% additional to primary extraction.[60] It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well.[61] In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.
Bio transformation into fuel
Main article: Carbon capture and utilization
A strain of the cyanobacterium Synechococcus elongatus has been genetically engineered to produce the fuels isobutyraldehyde and isobutanol from CO
2 using photosynthesis.[62]
Refrigerant
Comparison of phase diagrams of carbon dioxide (red) and water (blue) as a log-lin chart with phase transitions points at 1 atmosphere
Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C (−109.3 °F) at regular atmospheric pressure, regardless of the air temperature.
Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the discovery of R-12 and may enjoy a renaissance due to the fact that R134a contributes to climate change more than CO
2 does. Its physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bar (1880 psi), CO
2 systems require highly resistant components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, R744 operates more efficiently than systems using R134a. Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO
2-based beverage coolers and the U.S. Army is interested in CO
2 refrigeration and heating technology.[63][64]
The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. CO
2 is one discussed option.(see Sustainable automotive air conditioning)
Coal bed methane recovery
In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.[65]
Minor uses
A carbon dioxide laser.
Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers.
Carbon dioxide can be used as a means of controlling the pH of swimming pools,[66] by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely where it is used by some corals to build their skeleton.
Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.
Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO
2 include placing animals directly into a closed, prefilled chamber containing CO
2, or exposure to a gradually increasing concentration of CO
2. In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents.[67] However, there is opposition to the practice of using carbon dioxide for this, on the grounds that it is cruel.[52]
Carbon dioxide is also used in several related cleaning and surface preparation techniques.
In Earth's atmosphere
Main articles: Carbon dioxide in Earth's atmosphere and Carbon cycle
The Keeling Curve of atmospheric CO
2 concentrations measured at Mauna Loa Observatory
Carbon dioxide in Earth's atmosphere is a trace gas, currently (mid 2018) having a global average concentration of 409 parts per million by volume[68][69][70] (or 622 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the seasons, falling during the Northern Hemisphere spring and summer as plants consume the gas and rising during northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher[71] and indoors they can reach 10 times background levels.
Yearly increase of atmospheric CO
2: In the 1960s, the average annual increase was 35% of the 2009-2018 average.[72]
The concentration of carbon dioxide has risen due to human activities.[73] Combustion of fossil fuels and deforestation have caused the atmospheric concentration of carbon dioxide to increase by about 43% since the beginning of the age of industrialization.[74] Most carbon dioxide from human activities is released from burning coal and other fossil fuels. Other human activities, including deforestation, biomass burning, and cement production also produce carbon dioxide. Human activities emit about 29 billion tons of carbon dioxide per year, while volcanoes emit between 0.2 and 0.3 billion tons.[75][76] Human activities have caused CO
2 to increase above levels not seen in hundreds of thousands of years. Currently, about half of the carbon dioxide released from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans.[77][78][79][80]
While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm−1,[81] as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the surface, warming the surface and the lower atmosphere. Less energy reaches the upper atmosphere, which is therefore cooler because of this absorption.[82][83] Increases in atmospheric concentrations of CO
2 and other long-lived greenhouse gases such as methane, nitrous oxide and ozone have correspondingly strengthened their absorption and emission of infrared radiation, causing the rise in average global temperature since the mid-20th century. Carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of these other gases combined and because it has a long atmospheric lifetime (hundreds to thousands of years).
CO
2 in Earth's atmosphere if half of global-warming emissions are not absorbed.[77][78][79][80]
(NASA computer simulation).
Not only do increasing carbon dioxide concentrations lead to increases in global surface temperature, but increasing global temperatures also cause increasing concentrations of carbon dioxide. This produces a positive feedback for changes induced by other processes such as orbital cycles.[84] Five hundred million years ago the carbon dioxide concentration was 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then slowly declining with a particularly swift reduction occurring 49 million years ago.[85][86]
Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO
2 rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is dispersed by convection.[87] High concentrations of CO
2 produced by disturbance of deep lake water saturated with CO
2 are thought to have caused 37 fatalities at Lake Monoun, Cameroon in 1984 and 1700 casualties at Lake Nyos, Cameroon in 1986.[88]
In the oceans
Main article: Carbon cycle
Pterapod shell dissolved in seawater adjusted to an ocean chemistry projected for the year 2100.
Carbon dioxide dissolves in the ocean to form carbonic acid (H2CO3), bicarbonate (HCO3−) and carbonate (CO32−). There is about fifty times as much carbon dioxide dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about a third of CO
2 emitted by human activity.[89]
As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in surface waters since the carbonate ion is at supersaturating concentrations. However, as ocean pH falls, so does the concentration of this ion, and when carbonate becomes undersaturated, structures made of calcium carbonate are vulnerable to dissolution.[90] Corals,[91][92][93] coccolithophore algae,[94][95][96][97] coralline algae,[98] foraminifera,[99] shellfish[100] and pteropods[101] experience reduced calcification or enhanced dissolution when exposed to elevated CO
2.
Gas solubility decreases as the temperature of water increases (except when both pressure exceeds 300 bar and temperature exceeds 393 K, only found near deep geothermal vents)[102] and therefore the rate of uptake from the atmosphere decreases as ocean temperatures rise.
Most of the CO
2 taken up by the ocean, which is about 30% of the total released into the atmosphere,[103] forms carbonic acid in equilibrium with bicarbonate. Some of these chemical species are consumed by photosynthetic organisms that remove carbon from the cycle. Increased CO
2 in the atmosphere has led to decreasing alkalinity of seawater, and there is concern that this may adversely affect organisms living in the water. In particular, with decreasing alkalinity, the availability of carbonates for forming shells decreases,[104] although there's evidence of increased shell production by certain species under increased CO
2 content.[105]
NOAA states in their May 2008 "State of the science fact sheet for ocean acidification" that:
"The oceans have absorbed about 50% of the carbon dioxide (CO
2) released from the burning of fossil fuels, resulting in chemical reactions that lower ocean pH. This has caused an increase in hydrogen ion (acidity) of about 30% since the start of the industrial age through a process known as "ocean acidification." A growing number of studies have demonstrated adverse impacts on marine organisms, including:
The rate at which reef-building corals produce their skeletons decreases, while production of numerous varieties of jellyfish increases.
The ability of marine algae and free-swimming zooplankton to maintain protective shells is reduced.
The survival of larval marine species, including commercial fish and shellfish, is reduced."
Also, the Intergovernmental Panel on Climate Change (IPCC) writes in their Climate Change 2007: Synthesis Report:[106]
"The uptake of anthropogenic carbon since 1750 has led to the ocean becoming more acidic with an average decrease in pH of 0.1 units. Increasing atmospheric CO
2 concentrations lead to further acidification ... While the effects of observed ocean acidification on the marine biosphere are as yet undocumented, the progressive acidification of oceans is expected to have negative impacts on marine shell-forming organisms (e.g. corals) and their dependent species."
Some marine calcifying organisms (including coral reefs) have been singled out by major research agencies, including NOAA, OSPAR commission, NANOOS and the IPCC, because their most current research shows that ocean acidification should be expected to impact them negatively.[107]
Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano in the Marianas Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough.[108] The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006.[109]
Biological role
Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.
Photosynthesis and carbon fixation
Overview of photosynthesis and respiration. Carbon dioxide (at right), together with water, form oxygen and organic compounds (at left) by photosynthesis, which can be respired to water and (CO
2).
Overview of the Calvin cycle and carbon fixation
Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen is produced as a by-product.
Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO
2 and ribulose bisphosphate, as shown in the diagram at left.
RuBisCO is thought to be the single most abundant protein on Earth.[110]
Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales.[111] A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.
Plants can grow as much as 50 percent faster in concentrations of 1,000 ppm CO
2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients.[112] Elevated CO
2 levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO
2 in FACE experiments.[113][114]
Increased atmospheric CO
2 concentrations result in fewer stomata developing on plants[115] which leads to reduced water usage and increased water-use efficiency.[116] Studies using FACE have shown that CO
2 enrichment leads to decreased concentrations of micronutrients in crop plants.[117] This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.[118]
The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO
2.[119][120]
Plants also emit CO
2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of CO
2 each year, a mature forest will produce as much CO
2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants.[121] Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon[122] and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO
2 in the upper ocean and thereby promotes the absorption of CO
2 from the atmosphere.[123]
Toxicity
See also: Carbon dioxide poisoning
Main symptoms of carbon dioxide toxicity, by increasing volume percent in air.[124]
Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (410 ppm), depending on the location.[125][clarification needed]
CO
2 is an asphyxiant gas and not classified as toxic or harmful in accordance with Globally Harmonized System of Classification and Labelling of Chemicals standards of United Nations Economic Commission for Europe by using the OECD Guidelines for the Testing of Chemicals. In concentrations up to 1% (10,000 ppm), it will make some people feel drowsy and give the lungs a stuffy feeling.[124] Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour.[126] The physiological effects of acute carbon dioxide exposure are grouped together under the term hypercapnia, a subset of asphyxiation.
Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO
2 emissions from the nearby volcano Mt. Nyiragongo.[127] The Swahili term for this phenomenon is 'mazuku'.
Rising levels of CO
2 threatened the Apollo 13 astronauts who had to adapt cartridges from the command module to supply the carbon dioxide scrubber in the lunar module, which they used as a lifeboat.
Adaptation to increased concentrations of CO
2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance the effects of blood acidification (acidosis). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days.[128][129] Yet, other studies show a decrease in cognitive function even at much lower levels.[130][131] Also, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse such condition.
Below 1%
There are few studies of the health effects of long-term continuous CO
2 exposure on humans and animals at levels below 1%. Occupational CO
2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period.[132] At this CO
2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption.[133] Studies in animals at 0.5% CO
2 have demonstrated kidney calcification and bone loss after eight weeks of exposure.[134] A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000ppm) CO
2 likely due to CO
2 induced increases in cerebral blood flow.[130] Another study observed a decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm.[131]
Ventilation
CO
2 concentration meter using a nondispersive infrared sensor
Poor ventilation is one of the main causes of excessive CO
2 concentrations in closed spaces. Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO
2 concentration has stabilized) are sometimes used to estimate ventilation rates per person.[citation needed] Higher CO
2 concentrations are associated with occupant health, comfort and performance degradation.[135][136] ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000).
Miners, who are particularly vulnerable to gas exposure due to an insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp," "choke damp" or "stythe." Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The Davy lamp could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.
Human physiology
Content
Reference ranges or averages for partial pressures of carbon dioxide (abbreviated pCO
2) kPa mmHg
Venous blood carbon dioxide 5.5–6.8 41–51[137]
Alveolar pulmonary
gas pressures 4.8 36
Arterial blood carbon dioxide 4.7–6.0 35–45[137]
The body produces approximately 2.3 pounds (1.0 kg) of carbon dioxide per day per person,[138] containing 0.63 pounds (290 g) of carbon. In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs, resulting in lower concentrations in the arteries. The carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume.[139] In humans, the blood carbon dioxide contents is shown in the adjacent table:
Transport in the blood
CO
2 is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or venous blood).
Most of it (about 70% to 80%) is converted to bicarbonate ions HCO−
3 by the enzyme carbonic anhydrase in the red blood cells,[140] by the reaction CO
2 + H
2O → H
2CO
3 → H+
+ HCO−
3.
5–10% is dissolved in the plasma[140]
5–10% is bound to hemoglobin as carbamino compounds[140]
Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO
2 bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO
2 decreases the amount of oxygen that is bound for a given partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO
2 or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr effect.
Regulation of respiration
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Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its concentration is high, the capillaries expand to allow a greater blood flow to that tissue.
Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of CO
2 in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.
Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low-pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.[140]
The respiratory centers try to maintain an arterial CO
2 pressure of 40 mm Hg. With intentional hyperventilation, the CO
2 content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.
invisible substance termed a "gas"
or "wild spirit" (spiritus sylvestris).[23]
< >
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Plant food.
$BLONF Pr $0.1633
website low float 51,151,840
56% sell
filings and news 11/21/19
Gulf Cryo - Market Delivery Solutions in the Middle East
.....................................................
Other names
Carbonic acid gas
Carbonic anhydride
Carbonic oxide
Carbon oxide
Carbon(IV) oxide
Dry ice (solid phase)
In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products,[42] such as metal carbonates and bicarbonates.[citation needed] Some carboxylic acid derivatives such as sodium salicylate are prepared using CO
2 by the Kolbe-Schmitt reaction.[43]
In addition to conventional processes using CO
2 for chemical production, electrochemical methods are also being explored at a research level. In particular, the use of renewable energy for production of fuels from CO
2 (such as methanol) is attractive as this could result in fuels that could be easily transported and used within conventional combustion technologies but have no net CO
2 emissions.[44]
Foods
Carbon dioxide bubbles in a soft drink.
Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU[45] (listed as E number E290), US[46] and Australia and New Zealand[47] (listed by its INS number 290).
A candy called Pop Rocks is pressurized with carbon dioxide gas[48] at about 4 x 106 Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop.
Leavening agents cause dough to rise by producing carbon dioxide.[49] Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.
Beverages
Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.
Winemaking
Dry ice used to preserve grapes after harvest.
Carbon dioxide in the form of dry ice is often used during the cold soak phase in winemaking to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine.
Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.
Stunning animals
Carbon dioxide is often used to "stun" animals before slaughter.[50] "Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress.[51][52]
Inert gas
It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres.[citation needed] It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium.[citation needed] When used for MIG welding, CO
2 use is sometimes referred to as MAG welding, for Metal Active Gas, as CO
2 can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.
It is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi, 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of CO
2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines.[citation needed] High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy[53] and in the decaffeination of coffee beans.
Fire extinguisher
Use of a CO
2 fire extinguisher.
Carbon dioxide can be used to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances significantly and when the carbon dioxide disperses they are free to catch fire upon exposure to atmospheric oxygen. Their desirability in electrical fire stems from the fact that, unlike water or other chemical based methods, Carbon dioxide will not cause short circuits, leading to even more damage to equipment. Because it is a gas, it is also easy to dispense large amounts of the gas automatically in IT infrastructure rooms, where the fire itself might be hard to reach with more immediate methods because it is behind rack doors and inside of cases. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space.[54] International Maritime Organization standards also recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide based fire protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of CO
2 systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries.[55]
Supercritical CO2 as solvent
See also: Supercritical carbon dioxide
Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove caffeine from coffee.[15] Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides. It is also used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.
Agricultural and biological applications
Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional CO
2 to sustain and increase the rate of plant growth.[56][57] At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.[58]
It has been proposed that CO
2 from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel.[59]
Medical and pharmacological uses
In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O
2/CO
2 balance in blood.
Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses.
Oil recovery
Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by between 7% to 23% additional to primary extraction.[60] It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well.[61] In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.
Bio transformation into fuel
Main article: Carbon capture and utilization
A strain of the cyanobacterium Synechococcus elongatus has been genetically engineered to produce the fuels isobutyraldehyde and isobutanol from CO
2 using photosynthesis.[62]
Refrigerant
Comparison of phase diagrams of carbon dioxide (red) and water (blue) as a log-lin chart with phase transitions points at 1 atmosphere
Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C (−109.3 °F) at regular atmospheric pressure, regardless of the air temperature.
Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the discovery of R-12 and may enjoy a renaissance due to the fact that R134a contributes to climate change more than CO
2 does. Its physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bar (1880 psi), CO
2 systems require highly resistant components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, R744 operates more efficiently than systems using R134a. Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO
2-based beverage coolers and the U.S. Army is interested in CO
2 refrigeration and heating technology.[63][64]
The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. CO
2 is one discussed option.(see Sustainable automotive air conditioning)
Coal bed methane recovery
In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.[65]
Minor uses
A carbon dioxide laser.
Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers.
Carbon dioxide can be used as a means of controlling the pH of swimming pools,[66] by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely where it is used by some corals to build their skeleton.
Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.
Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO
2 include placing animals directly into a closed, prefilled chamber containing CO
2, or exposure to a gradually increasing concentration of CO
2. In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents.[67] However, there is opposition to the practice of using carbon dioxide for this, on the grounds that it is cruel.[52]
Carbon dioxide is also used in several related cleaning and surface preparation techniques.
In Earth's atmosphere
Main articles: Carbon dioxide in Earth's atmosphere and Carbon cycle
The Keeling Curve of atmospheric CO
2 concentrations measured at Mauna Loa Observatory
Carbon dioxide in Earth's atmosphere is a trace gas, currently (mid 2018) having a global average concentration of 409 parts per million by volume[68][69][70] (or 622 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the seasons, falling during the Northern Hemisphere spring and summer as plants consume the gas and rising during northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher[71] and indoors they can reach 10 times background levels.
Yearly increase of atmospheric CO
2: In the 1960s, the average annual increase was 35% of the 2009-2018 average.[72]
The concentration of carbon dioxide has risen due to human activities.[73] Combustion of fossil fuels and deforestation have caused the atmospheric concentration of carbon dioxide to increase by about 43% since the beginning of the age of industrialization.[74] Most carbon dioxide from human activities is released from burning coal and other fossil fuels. Other human activities, including deforestation, biomass burning, and cement production also produce carbon dioxide. Human activities emit about 29 billion tons of carbon dioxide per year, while volcanoes emit between 0.2 and 0.3 billion tons.[75][76] Human activities have caused CO
2 to increase above levels not seen in hundreds of thousands of years. Currently, about half of the carbon dioxide released from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans.[77][78][79][80]
While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm−1,[81] as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the surface, warming the surface and the lower atmosphere. Less energy reaches the upper atmosphere, which is therefore cooler because of this absorption.[82][83] Increases in atmospheric concentrations of CO
2 and other long-lived greenhouse gases such as methane, nitrous oxide and ozone have correspondingly strengthened their absorption and emission of infrared radiation, causing the rise in average global temperature since the mid-20th century. Carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of these other gases combined and because it has a long atmospheric lifetime (hundreds to thousands of years).
CO
2 in Earth's atmosphere if half of global-warming emissions are not absorbed.[77][78][79][80]
(NASA computer simulation).
Not only do increasing carbon dioxide concentrations lead to increases in global surface temperature, but increasing global temperatures also cause increasing concentrations of carbon dioxide. This produces a positive feedback for changes induced by other processes such as orbital cycles.[84] Five hundred million years ago the carbon dioxide concentration was 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then slowly declining with a particularly swift reduction occurring 49 million years ago.[85][86]
Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO
2 rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is dispersed by convection.[87] High concentrations of CO
2 produced by disturbance of deep lake water saturated with CO
2 are thought to have caused 37 fatalities at Lake Monoun, Cameroon in 1984 and 1700 casualties at Lake Nyos, Cameroon in 1986.[88]
In the oceans
Main article: Carbon cycle
Pterapod shell dissolved in seawater adjusted to an ocean chemistry projected for the year 2100.
Carbon dioxide dissolves in the ocean to form carbonic acid (H2CO3), bicarbonate (HCO3−) and carbonate (CO32−). There is about fifty times as much carbon dioxide dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about a third of CO
2 emitted by human activity.[89]
As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in surface waters since the carbonate ion is at supersaturating concentrations. However, as ocean pH falls, so does the concentration of this ion, and when carbonate becomes undersaturated, structures made of calcium carbonate are vulnerable to dissolution.[90] Corals,[91][92][93] coccolithophore algae,[94][95][96][97] coralline algae,[98] foraminifera,[99] shellfish[100] and pteropods[101] experience reduced calcification or enhanced dissolution when exposed to elevated CO
2.
Gas solubility decreases as the temperature of water increases (except when both pressure exceeds 300 bar and temperature exceeds 393 K, only found near deep geothermal vents)[102] and therefore the rate of uptake from the atmosphere decreases as ocean temperatures rise.
Most of the CO
2 taken up by the ocean, which is about 30% of the total released into the atmosphere,[103] forms carbonic acid in equilibrium with bicarbonate. Some of these chemical species are consumed by photosynthetic organisms that remove carbon from the cycle. Increased CO
2 in the atmosphere has led to decreasing alkalinity of seawater, and there is concern that this may adversely affect organisms living in the water. In particular, with decreasing alkalinity, the availability of carbonates for forming shells decreases,[104] although there's evidence of increased shell production by certain species under increased CO
2 content.[105]
NOAA states in their May 2008 "State of the science fact sheet for ocean acidification" that:
"The oceans have absorbed about 50% of the carbon dioxide (CO
2) released from the burning of fossil fuels, resulting in chemical reactions that lower ocean pH. This has caused an increase in hydrogen ion (acidity) of about 30% since the start of the industrial age through a process known as "ocean acidification." A growing number of studies have demonstrated adverse impacts on marine organisms, including:
The rate at which reef-building corals produce their skeletons decreases, while production of numerous varieties of jellyfish increases.
The ability of marine algae and free-swimming zooplankton to maintain protective shells is reduced.
The survival of larval marine species, including commercial fish and shellfish, is reduced."
Also, the Intergovernmental Panel on Climate Change (IPCC) writes in their Climate Change 2007: Synthesis Report:[106]
"The uptake of anthropogenic carbon since 1750 has led to the ocean becoming more acidic with an average decrease in pH of 0.1 units. Increasing atmospheric CO
2 concentrations lead to further acidification ... While the effects of observed ocean acidification on the marine biosphere are as yet undocumented, the progressive acidification of oceans is expected to have negative impacts on marine shell-forming organisms (e.g. corals) and their dependent species."
Some marine calcifying organisms (including coral reefs) have been singled out by major research agencies, including NOAA, OSPAR commission, NANOOS and the IPCC, because their most current research shows that ocean acidification should be expected to impact them negatively.[107]
Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano in the Marianas Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough.[108] The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006.[109]
Biological role
Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.
Photosynthesis and carbon fixation
Overview of photosynthesis and respiration. Carbon dioxide (at right), together with water, form oxygen and organic compounds (at left) by photosynthesis, which can be respired to water and (CO
2).
Overview of the Calvin cycle and carbon fixation
Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen is produced as a by-product.
Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO
2 and ribulose bisphosphate, as shown in the diagram at left.
RuBisCO is thought to be the single most abundant protein on Earth.[110]
Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales.[111] A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.
Plants can grow as much as 50 percent faster in concentrations of 1,000 ppm CO
2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients.[112] Elevated CO
2 levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO
2 in FACE experiments.[113][114]
Increased atmospheric CO
2 concentrations result in fewer stomata developing on plants[115] which leads to reduced water usage and increased water-use efficiency.[116] Studies using FACE have shown that CO
2 enrichment leads to decreased concentrations of micronutrients in crop plants.[117] This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.[118]
The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO
2.[119][120]
Plants also emit CO
2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of CO
2 each year, a mature forest will produce as much CO
2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants.[121] Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon[122] and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO
2 in the upper ocean and thereby promotes the absorption of CO
2 from the atmosphere.[123]
Toxicity
See also: Carbon dioxide poisoning
Main symptoms of carbon dioxide toxicity, by increasing volume percent in air.[124]
Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (410 ppm), depending on the location.[125][clarification needed]
CO
2 is an asphyxiant gas and not classified as toxic or harmful in accordance with Globally Harmonized System of Classification and Labelling of Chemicals standards of United Nations Economic Commission for Europe by using the OECD Guidelines for the Testing of Chemicals. In concentrations up to 1% (10,000 ppm), it will make some people feel drowsy and give the lungs a stuffy feeling.[124] Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour.[126] The physiological effects of acute carbon dioxide exposure are grouped together under the term hypercapnia, a subset of asphyxiation.
Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO
2 emissions from the nearby volcano Mt. Nyiragongo.[127] The Swahili term for this phenomenon is 'mazuku'.
Rising levels of CO
2 threatened the Apollo 13 astronauts who had to adapt cartridges from the command module to supply the carbon dioxide scrubber in the lunar module, which they used as a lifeboat.
Adaptation to increased concentrations of CO
2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance the effects of blood acidification (acidosis). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days.[128][129] Yet, other studies show a decrease in cognitive function even at much lower levels.[130][131] Also, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse such condition.
Below 1%
There are few studies of the health effects of long-term continuous CO
2 exposure on humans and animals at levels below 1%. Occupational CO
2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period.[132] At this CO
2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption.[133] Studies in animals at 0.5% CO
2 have demonstrated kidney calcification and bone loss after eight weeks of exposure.[134] A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000ppm) CO
2 likely due to CO
2 induced increases in cerebral blood flow.[130] Another study observed a decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm.[131]
Ventilation
CO
2 concentration meter using a nondispersive infrared sensor
Poor ventilation is one of the main causes of excessive CO
2 concentrations in closed spaces. Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO
2 concentration has stabilized) are sometimes used to estimate ventilation rates per person.[citation needed] Higher CO
2 concentrations are associated with occupant health, comfort and performance degradation.[135][136] ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000).
Miners, who are particularly vulnerable to gas exposure due to an insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp," "choke damp" or "stythe." Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The Davy lamp could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.
Human physiology
Content
Reference ranges or averages for partial pressures of carbon dioxide (abbreviated pCO
2) kPa mmHg
Venous blood carbon dioxide 5.5–6.8 41–51[137]
Alveolar pulmonary
gas pressures 4.8 36
Arterial blood carbon dioxide 4.7–6.0 35–45[137]
The body produces approximately 2.3 pounds (1.0 kg) of carbon dioxide per day per person,[138] containing 0.63 pounds (290 g) of carbon. In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs, resulting in lower concentrations in the arteries. The carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume.[139] In humans, the blood carbon dioxide contents is shown in the adjacent table:
Transport in the blood
CO
2 is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or venous blood).
Most of it (about 70% to 80%) is converted to bicarbonate ions HCO−
3 by the enzyme carbonic anhydrase in the red blood cells,[140] by the reaction CO
2 + H
2O → H
2CO
3 → H+
+ HCO−
3.
5–10% is dissolved in the plasma[140]
5–10% is bound to hemoglobin as carbamino compounds[140]
Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO
2 bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO
2 decreases the amount of oxygen that is bound for a given partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO
2 or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr effect.
Regulation of respiration
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Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its concentration is high, the capillaries expand to allow a greater blood flow to that tissue.
Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of CO
2 in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.
Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low-pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.[140]
The respiratory centers try to maintain an arterial CO
2 pressure of 40 mm Hg. With intentional hyperventilation, the CO
2 content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.
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