TQD Stress Sensor apps whitepaper (2018): "Discus
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Posted On: 06/22/2019 2:31:21 PM
TQD Stress Sensor apps whitepaper (2018):
"Discussion
In this work, we have employed experimental opto-mechanical and mechanical characterization to demonstrate that branched tQDs exhibit excellent stress sensing capabilities to track mechanical stress–strain behavior in a wide spectrum of polymeric systems. Specifically, we have studied 17 tQD-polymer systems covering over eight polymer host matrices, multiple tQD-polymer interfacial chemistries, several tQD concentrations and dispersions, and more than four orders of magnitude variation in host matrix Young’s modulus. We find that changing the Young’s modulus of the host matrix varies the tQD stress response, or pressure coefficient, by over three orders of magnitude. We present a method to functionalize tQDs with different polymeric ligands, achieving excellent dispersion of tQDs in multiple polymer matrices. Clear, cyclable stress sensing is observed in all polymers, with the mechanical properties of the polymers not degraded at all by the tQD additions. We further determine the strain transfer efficiency from the polymer to the tQD, finding that the efficiency increases for stiffer host matrix materials. Our results also represent a validation of the Mori-Tanaka theory for such systems. These findings indicate the high versatility of tQD stress sensors to a wide range of structural and biomedical applications as well as to fundamental polymer dynamics studies." https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5861061/
"Discussion
In this work, we have employed experimental opto-mechanical and mechanical characterization to demonstrate that branched tQDs exhibit excellent stress sensing capabilities to track mechanical stress–strain behavior in a wide spectrum of polymeric systems. Specifically, we have studied 17 tQD-polymer systems covering over eight polymer host matrices, multiple tQD-polymer interfacial chemistries, several tQD concentrations and dispersions, and more than four orders of magnitude variation in host matrix Young’s modulus. We find that changing the Young’s modulus of the host matrix varies the tQD stress response, or pressure coefficient, by over three orders of magnitude. We present a method to functionalize tQDs with different polymeric ligands, achieving excellent dispersion of tQDs in multiple polymer matrices. Clear, cyclable stress sensing is observed in all polymers, with the mechanical properties of the polymers not degraded at all by the tQD additions. We further determine the strain transfer efficiency from the polymer to the tQD, finding that the efficiency increases for stiffer host matrix materials. Our results also represent a validation of the Mori-Tanaka theory for such systems. These findings indicate the high versatility of tQD stress sensors to a wide range of structural and biomedical applications as well as to fundamental polymer dynamics studies." https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5861061/
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