New Thin-Film Solar Cell Study Finds Greener Manuf
Post# of 22465
Posted On: 11/16/2015 9:39:52 AM
New Thin-Film Solar Cell Study Finds Greener Manufacturing Alternative
The new thin-film solar cell study from Oak Ridge National Laboratory (ORNL) indicates that the industry could transition out of its dependency on toxic solvents in favor of a more environmentally relaxed solvent called a surfactant, which is fancyspeak for detergent.
http://cleantechnica.com/2015/10/07/new-thin-...ternative/
.....Detergent; Did anyone think of Michael Wong and tetrapod QDs when that was mentioned?
https://www.ornl.gov/news/ornl-researchers-fi...plications
.....this article smokes, imo
Controlling molecular ordering in solution-state conjugated polymers
J. Zhu,a Y. Han,b R. Kumar,ac Y. He,a K. Hong,a P. V. Bonnesen,a B. G. Sumpter,ac S. C. Smith,d G. S. Smith,b I. N. Ivanov*a and C. Do*b
Rationally encoding molecular interactions that can control the assembly structure and functional expression in a solution of conjugated polymers hold great potential for enabling optimal organic optoelectronic and sensory materials. In this work, we show that thermally-controlled and surfactant-guided assembly of water-soluble conjugated polymers in aqueous solution is a simple and effective strategy to generate optoelectronic materials with the desired molecular ordering. We have studied a conjugated polymer consisting of a hydrophobic thiophene backbone and hydrophilic, thermo-responsive ethylene oxide side groups, which shows a step-wise, multi-dimensional assembly in water. By incorporating the polymer into phase-segregated domains of an amphiphilic surfactant in solution, we demonstrate that both chain conformation and degree of molecular ordering of the conjugated polymer can be tuned in hexagonal, micellar and lamellar phases of the surfactant solution. The controlled molecular ordering in conjugated polymer assembly is demonstrated as a key factor determining the electronic interaction and optical function.
http://pubs.rsc.org/en/Content/ArticleLanding...ivAbstract
The new thin-film solar cell study from Oak Ridge National Laboratory (ORNL) indicates that the industry could transition out of its dependency on toxic solvents in favor of a more environmentally relaxed solvent called a surfactant, which is fancyspeak for detergent.
http://cleantechnica.com/2015/10/07/new-thin-...ternative/
.....Detergent; Did anyone think of Michael Wong and tetrapod QDs when that was mentioned?
https://www.ornl.gov/news/ornl-researchers-fi...plications
.....this article smokes, imo
Controlling molecular ordering in solution-state conjugated polymers
J. Zhu,a Y. Han,b R. Kumar,ac Y. He,a K. Hong,a P. V. Bonnesen,a B. G. Sumpter,ac S. C. Smith,d G. S. Smith,b I. N. Ivanov*a and C. Do*b
Rationally encoding molecular interactions that can control the assembly structure and functional expression in a solution of conjugated polymers hold great potential for enabling optimal organic optoelectronic and sensory materials. In this work, we show that thermally-controlled and surfactant-guided assembly of water-soluble conjugated polymers in aqueous solution is a simple and effective strategy to generate optoelectronic materials with the desired molecular ordering. We have studied a conjugated polymer consisting of a hydrophobic thiophene backbone and hydrophilic, thermo-responsive ethylene oxide side groups, which shows a step-wise, multi-dimensional assembly in water. By incorporating the polymer into phase-segregated domains of an amphiphilic surfactant in solution, we demonstrate that both chain conformation and degree of molecular ordering of the conjugated polymer can be tuned in hexagonal, micellar and lamellar phases of the surfactant solution. The controlled molecular ordering in conjugated polymer assembly is demonstrated as a key factor determining the electronic interaction and optical function.
http://pubs.rsc.org/en/Content/ArticleLanding...ivAbstract
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